First heterogenisation of Rh-MeDuPHOS by occlusion in PDMS (polydimethylsiloxane) membranes Academic Article uri icon

abstract

  • First heterogenisation of Rh–MeDuPHOS by occlusion in PDMS (polydimethylsiloxane) membranes … Ivo Vankelecom,*a Adi Wolfson,b Shimona Geresh,b Miron Landau,b Moshe Gottliebb and Moti Hershkovitzb a Centre for Surface Chemistry and Catalysis, Faculty of Agricultural and Applied Biological Sciences, Katholieke Universiteit Leuven, Kardinaal Mercierlaan 92, 3001 Leuven, Belgium. E-mail: ivo.vankelecom@agr.kuleuven.ac.be b Blechner Center, Chemical Engineering Department, Ben-Gurion University of the Negev, PO Box 653, Beer-Sheva, Israel … Received (in Cambridge, UK) 6th September 1999, Accepted 26th October 1999 … The first heterogeneous system of Rh–MeDuPHOS, ob- tained by occlusion of the complex in a PDMS membrane, is reported and tested in the hydrogenation of methylacetoace- tate (MAA) … Asymmetric synthesis with homogeneous chiral complexes is one of the best methods to prepare …

publication date

  • January 1, 1999