In situ EPR study of sol-gel processes Academic Article uri icon

abstract

  • Abstract The electron paramagnetic resonance (EPR) spectra of the stable free radical (4- oxo-Tempo) were investigated during sol-gel-xerogel transition both for non-doped and o- phenanthroline-doped silica glasses. Gradual changes in linewidths, rotation correlation time, isotropic hyperfine interaction parameters and integral line intensities were observed. These spectral changes reflect variations in the composition, effective viscosity and polarity of the cage media in the vicinity of the probe. The EPR spectroscopy of stable free …

publication date

  • September 2, 1994