Liquidus projection of Al-rich corner of the ternary Al-Fe-U system Academic Article uri icon

abstract

  • Microstructures of the solidified Al–Fe–U ternary alloys have been examined using optical and scanning electron microscopy. Phase content and chemical composition of the different phases present was determined by Energy-Dispersive Spectrometry and X-ray diffraction. Differential Scaling Calorimetry was used for analysis of thermal effects accompanied phase transformations in the course of solidification. On the basis of results obtained liquidus projection was constructed for Al-rich corner of the Al–Fe–U system. Two ternary peritectic reactions have been found to occur. It was proposed that 1) an orthorhombic phase UFe 2 Al 10 is formed by ternary peritectic reaction: UAl 3+ Al 13 Fe 4+ Al (L)→ UFe 2 Al 10 within the temperature range of 850–1157° C; 2) tetragonal phase U 2 FeAl 20 is formed by ternary peritectic reaction: UAl 4+ UFe 2 Al 10+ Al (L)→ U 2 FeAl 20 at a temperature of about …

publication date

  • January 1, 2010