New possible mode of ligand–metal cooperation in PC (sp 3) P pincer complexes Academic Article uri icon

abstract

  • Ligand–metal cooperation in iridium and platinum complexes bearing tricyclic dibenzobarrelene-based PC (sp3) P pincer ligands is discussed. We demonstrated that the carbon–metal bond in these complexes may be efficiently cleaved and regenerated via1, 2- addition/elimination reactions.

publication date

  • January 1, 2011