Relationships between gas-liquid interfacial surface area, liquid saturation, and light transmission in variably saturated porous media: RELATIONSHIPS IN VARIABLY SATURATED MEDIA Academic Article uri icon

abstract

  • [1] Liquid saturation and gas-liquid interfacial area are important parameters for evaluating the transport and fate of contaminants in unsaturated subsurface environments. Recent findings indicate that interfacial surface area controls the relative degree of transmitted light in laboratory systems containing translucent porous media. Equations are derived to estimate the specific gas-liquid interfacial area from the area under the primarydrainage branch of the Seff-h characteristic curve as parameterized using common water retention functions. The total area under the curve provides the maximum available specific gas-liquid interfacial area available at residual saturation, which can be incorporated into the relationship to determine the gas-liquid interfacial area at intermediate degrees of saturation via light transmission. Experimental results, and analysis of external data sets, support these findings. Closed-form relationships are presented as enhancements to a recent method for determination of liquid saturations above residual using light transmission. A physically based model is developed and tested for the quantification of liquid contents below residual saturation. INDEX TERMS: 1829 Hydrology: Groundwater hydrology; 1866 Hydrology: Soil moisture; 1875 Hydrology: Unsaturated zone; 1894 Hydrology: Instruments and techniques; KEYWORDS: light transmission, gas-liquid interfacial surface area, liquid saturation, residual saturation, unsaturated porous media, characteristic curve

publication date

  • January 1, 2002