A NEW CLASS OF HETEROBICYCLIC SYSTEMS : DIOXADIAZADECALINS Academic Article uri icon

abstract

  • Two entirely new, fused di(oxazane) heterocycles, the diastereomeric 1,5-dioxa-3,7-diazadecalin (DODAD) and 1,5-diaza-3,7-dioxadecalin (DADOD) systems ( 3 , 4 , 6 and 7 ) were prepared and probed, both experimentally and computationally. The enantiopure 2,6-di(p-nitrophenyl)- cis -DODAD and - cis -DADOD derivatives ( 10, 11 ) underwent X-ray analysis.

publication date

  • January 1, 1997