A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor Academic Article uri icon

abstract

  • A 1,3-dipolar cycloaddition reaction taking place quantitatively between propiolic acid “guests” and azide functions previously attached to binding sites within the cavity of a {Mo132}-type Keplerate reproducibly gives a 2 : 1 ratio of 1,4- and 1,5-triazoles.

publication date

  • January 1, 2012